Abstract
Palladium coordinated in N-heterocyclic carbene-functionalized porous organic polymer (Pd@PQP-NHC) was successfully prepared via a facile copolymerization and successive immobilization method. The obtained Pd@PQP-NHC that featured relatively large surface area, hierarchical pore structure, and strong electron interaction between Pd species and bis-NHC ligand, displayed very high catalytic activity for the oxidative carbonylation of glycerol. A 0.025 mol% of Pd loading was sufficient for 96% conversion of glycerol with a high turnover frequency (TOF) of 1901 h−1. Moreover, the catalyst could be reused at least nine consecutive recycles without obvious loss of its initial activity.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Disclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.