Abstract
The first example of Pd(II)-catalyzed arylation of 2,2'-bipyridine-6-carboxamides via a rollover cyclometalation pathway is reported. A diverse range of (hetero)aryl iodides could be directly coupled with various 2,2'-bipyridine-6-carboxamides in exclusive site-selectivity, which offers a distinct entry to arylated 2,2'-bipyridine-6-carboxamides. A preliminary mechanistic study supports the Pd(II)-rollover cyclometalation pathway.
Full Text 
Sign-in/Register to access full text options
Sign-in/Register to access full text options 
Published version (
Free)
Free) 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a call
