Abstract
The reaction of α-chloromethylnaphthalene with various olefins in the presence of palladium acetate produces three different kinds of products. The coupling products with the olefinic bond conjugated to the naphthalene ring are the major products for the reactions of most olefins. An unusual rearrangement product formed via a cyclopalladation intermediate is isolated from the reactions of the two N-vinyl olefins.
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