Abstract
A palladium-catalyzed perfluoroalkylative carbonylation of 2-allylaryl trifluoromethanesulfonates has been developed. A range of 2-allyl trifluoromethanesulfonates, perfluoroalkyl halides, and amines were applied in this tandem procedure to provide the corresponding β-perfluoroalkyl amides with good functional group tolerance and high chemoselectivity. The final products were controlled by the base applied.
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