Abstract
A novel experimental procedure to obtain α-benzyl-β-keto esters from the Heck reaction between arenediazonium tetrafluoroborate salts and Baylis–Hillman (BH) adducts in the presence of Pd(OAc) 2 as catalyst is described. The methodology is simple, straightforward and the use of arenediazonium salts as opposed to conventional arylhalides/triflates over the usual Heck reaction is highlighted.
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