Abstract
(R)- and (S)-3,4,5-(MeO)3 -MeOBIPHEP have been identified as the efficient chiral ligands for the palladium-catalyzed highly enantioselective synthesis of 2,3-allenoates from different types of easily available racemic propargylic carbonates with 90-98 % ee and decent yields. The potential of the products was demonstrated with high chirality transfer efficiency.
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