Abstract
The Suzuki–Miyaura-type cross-coupling reaction of potassium alkyltrifluoroborates with various alkenyl bromides in the presence of 10 mol % of PdCl 2(dppf)·CH 2Cl 2 and 3.0 equiv of Cs 2CO 3 in aqueous toluene at 80 °C provided the desired compounds in 63–95% yields. A variety of functional groups in the potassium alkyltrifluoroborates were tolerated under the basic conditions.
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