Abstract
AbstractA regioselective C1‐olefination of indolizines enabled by PdII‐catalyzed non‐directed C−H activation has been developed. Molecular oxygen is employed in this protocol as the terminal oxidant and with a catalytic amount CuII salt as the co‐oxidant. A broad range of simple and highly fused indolizine substrates were compatible with the reaction conditions, enabling the straightforward synthesis of valuable C1‐substituted indolizine derivatives.
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