Abstract
The asymmetric cyclocarbonylation reaction of allyl naphthol catalyzed by palladium complexes and chiral phosphine is reported. The reaction was performed under syn-gas conditions at relatively mild experimental conditions (80100 °C, 300600 psi (1 psi = 6.895 kPa)) in CH2Cl2 as the solvent.Key words: enantioselective, carbonylation, cyclocarbonylation, lactones, palladium acetate.
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