Abstract
ESI-MS monitoring of the title reaction has led to the discovery that dinuclear allyl-bridged PdI complexes are formed reversibly in substantial amounts during catalysis (see scheme; Bz=benzoyl). The structure of one such complex was determined by X-ray analysis (see picture; P yellow, N blue, O red, Pd dark gray). Upon consumption of the starting materials a new dinuclear complex resulting from reductive C[BOND]Cl bond cleavage of CH2Cl2 was observed.
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