Abstract
Useful intermediates: Addition of silyl-substituted chloroalkynes to terminal alkynes, namely chloroalkynylation, proceeds under palladium catalysis to afford (Z)-1-chloro-1,3-enynes (see scheme). The carbon–chlorine bond of the adducts is easily convertible to a carbon–carbon bond by using palladium-catalyzed cross-coupling reactions to provide a variety of 1,3-enynes.
Sign-in/Register to access full text options 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
