Abstract
The Pd(0) and Pd(II)-catalysed cyclisation/functionalisation reactions of acyclic carbohydrate-derived 1,1-diacetoxy-2,7-diene and 1,1-diacetoxy-2-en-7-yne compounds proceeded in a stereospecific fashion to furnish chiral. multi-functionalised furanoid and cyclopentanoid products. The products contained valuable enolacetate moieties. which can be further elaborated to enable the facile entry to an array of substituted five membered ring compounds.
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