Abstract
A simple and efficient procedure has been developed for the direct formation of epi-4-alkylamino- N-acetylneuraminic acid derivatives as potential inhibitors of influenza neuraminidases. The allylic amination of oxazoline 6 has been effected with a series of primary and secondary amines in the presence of catalytic Pd(π-allyl) 2(Et 3P) 2 to give the corresponding 4- epi-alkylamino products in a stereoselective and regiospecific manner.
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