Paleoenvironmental changes during the early Toarcian Oceanic Anoxic Event: Insights into organic carbon distribution and controlling mechanisms in the eastern Tethys

Abstract

• Unlike N Europe, TOC contents are significantly varied in lower Toarcian sediments of the eastern Tethys . • Anoxic, but non-sulfidic conditions prevailing during the T-OAE. • Humid climates promoted moderate continental weathering during the T-OAE. • Marine productivity was commonly high during the T-OAE in the eastern Tethyssouthern Qiangtang Basin. • Organic carbon burial and oil shale accumulation sustained by increased primary productivity. The Toarcian Oceanic Anoxic Event (T-OAE; Early Jurassic, ca. 183 Ma) represents an intense Mesozoic organic carbon burial event that was associated with the formation of oxygen-deficient conditions at paleo-shelf seas, as well as in lacustrine settings. Global scale increase in organic carbon accumulation occurred in connection with profound changes in climate conditions and perturbations of biogeochemical cycles. This study presents geochemical data for lower Toarcian and Bajocian-Bathonian sediments exposed in the Bilong Co section, located in the southern Qiangtang Basin of central Tibet. During Early and Middle Jurassic times, the study site was located in the north-eastern marine of the Tethys Ocean. A total of 83 rock samples, spanning the Quse (lower Toarcian) and Sewa formations (upper Bajocian-Bathonian), were analyzed for their total organic carbon (TOC) content, carbon isotopes of bulk carbonate and kerogen, as well as major and trace elements. Data allowed to assess changes in the environmental conditions in the eastern Tethys Ocean and further allowed to reconstruct changes in paleo-weathering conditions, marine primary productivity, and redox regimes that occurred in association with the T-OAE. In addition, factors that controlled the accumulation of organic material in the sediment are discussed. Enrichment factors (EF) of redox-sensitive trace elements, their relationship with TOC, and C org /P total molar ratio attest to predominantly anoxic pore and bottom waters in southern Qiangtang Basin during the T-OAE. On the contrary, oxic conditions prevailed during pre- and post-T-OAE times. During the T-OAE, the development of anoxic conditions were most likely linked to an increase in marine primary productivity, as revealed by C org /P total molar ratio, as well as Al-normalized Ba, and Zn concentrations, and their relationship with TOC. Data further attest to a moderate to low marine primary productivity during pre- and post-TOAE times. During the T-OAE, an increase in the marine primary productivity was linked to intensified continental weathering, facilitated by semi-humid climate conditions. Compilation of TOC data from various depositional settings in the eastern Tethys Ocean revealed a high spatial variability, highlighting the importance of local intrabasinal processes on organic matter accumulation.