Paleoceanographic evolution in the South Atlantic Ocean (Kwanza Basin, Angola) during its post-salt foundering

Abstract

Calcareous nannofossil distribution, environmental magnetism, and geochemical data provide stratigraphic evidence concerning the paleoceanographic changes across the lower/middle Albian and the Oceanic Anoxic Event 1b (OAE1b, Kilian Level) at South Atlantic Ocean. In this study, we analyzed samples from the sedimentary records at Deep Sea Drilling Project (DSDP) Site 364, Kwanza Basin, Angola. This section is associated with the initial phases of evolution of the South Atlantic Ocean, characterized by the deposition of extensive evaporite layers under restricted marine conditions, which were preserved in many sedimentary basins of the Brazilian and African continental margins. The open marine conditions that followed this period are recorded in the sequences of limestones interbedded with organic matter-rich black shales. In the Kwanza Basin, Site 364 contains a well-preserved sedimentary record of these post-salt sequences. In this study, we address the Lower Cretaceous sedimentary records at Site 364 from a paleoceanographic perspective, investigating the influence of OAE1b and local paleoenvironmental conditions. Our data analysis indicates a progressive reduction in hypersaline conditions during the lower/middle Albian. In these conditions, five paleoceanographic intervals (PIs) were described, which show different evidence of dysoxia/anoxia and salinity fluctuations, euxinic intervals, surface-water temperature changes, and hydrothermal activity signals, as well as possible ocean acidification episodes. These paleoceanographic conditions at Site 364 are associated with a stratified thermocline composed of warm surface-water from the North Atlantic (Western Tethys) and cool deep-water incursions from the Austral Atlantic, which strongly affected the composition of the calcareous nannofossil assemblages. We propose that the lower/middle Albian paleogeographic and paleoceanographic conditions observed in the Kwanza Basin were likely related not only to local events linked to the early development of the South Atlantic, but also to the OAE1b - Kilian Level recognized in several basins from around the world.