Abstract
The present study deals with the synthesis of paddle-wheel structured binuclear Mn-TP complex via molecular adduct with chloride salt of Mn. We report a novel N,N,N′,N′- tetramethylbutane1,4-diammonium bis(4-amino benzoate) C8H22N22+. 2C7H6NO2−. 2.25H2O (TP) and its binuclear metal–organic framework having a channel for hydrophilic guest molecules. Another interesting structural feature of ligand TP has the hexagonal cavity along with the stream of four waters molecules in the host hydrophilic channels. Both experimental and theoretical studies of bonding parameters, as well as optimized structure for Mn-TP complex were in good agreement with each other. Both Mn atoms lead to closed polyhedra with four PABA molecules and chlorine atoms.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
