Abstract

Analytical solutions for either the shear stress or the normal stress differences in large-amplitude oscillatory shear flow, both for continuum or molecular models, often take the form of the first few terms of a power series in the shear rate amplitude. Here, we explore improving the accuracy of these truncated series by replacing them with ratios of polynomials. Specifically, we examine replacing the truncated series solution for the corotational Maxwell model with its Pade approximants for the shear stress response and for the normal stress differences. We find these Pade approximants to agree closely with the corresponding exact solution, and we learn that with the right approximants, one can nearly eliminate the inaccuracies of the truncated expansions.

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