Abstract
Reaction of Cu2(OH)2CO3 and 3-amino-1,2,4-triazole (Hatz) in aqueous ammonia under hydrothermal condition generates copper(I) triazolate with three different forms, namely α-[Cu(atz)] (1α, P21/c, a = 3.6325(6) A, b = 10.284(2) A, c = 10.481(2) A, β = 97.379(3)°, V = 388.3(1) A3), β-[Cu(atz)] (1β, Pbca, a = 10.3115(9) A, b = 10.498(1) A, c = 14.744(1) A, V = 1596.0(3) A3), and γ-[Cu(atz)] (1γ, P21/c, a = 8.4608(7) A, b = 10.3198(9) A, c = 10.5728(9) A, β = 118.944(8)°, V = 807.8(1) A3). Structural analyses revealed that the three structures have the same chemical composition and essentially identical local and two-dimensional coordination structures, and their structural differences only arise from different packing fashions of the curved layers, which is a new mode of supramolecular isomerism in coordination polymers. The photoluminescence property of the title compound was also studied.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
