Abstract
Polymerization of methyl acrylate (MA), initiated by p-acetyl benzylidene triphenylarsonium ylide (p-ABTAY) in dioxan at (60 ± 1)°C for 1 h, follows nonideal kinetics (Rp ∝ [I]0.21[M]1.40) due to primary radical termination as well as degradative chain transfer reaction. The polymerization proceeded upto 20.49% conversion without gelation and results in the polymer of high molecular weight 98,000. The overall activation energy and the value of kp2/kt are 14 kJ mol–1 and 18.75 × 10–6 L mol–1 s–1, respectively. The ylide dissociates to form phenyl radical, which initiates the polymerization of MA. © 2008 Wiley Periodicals, Inc. J Appl Polym Sci, 2008
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