Ozone β-Cyclodextrin Inclusion Complex Characterization and Application in the Remediation of Total Petroleum Hydrocarbons

Abstract

Green remediation is essential in the current practice of water resources management. In this study, a series of ozone β-cyclodextrin (O3-βCD) inclusion complexes were prepared under a selected range of different ozone concentrations, β-CD concentrations, and solution pHs to test their ozone release rates and efficiencies in the treatment of total petroleum hydrocarbons (TPH) in water. The main objectives of this study are to characterize the O3-βCD system, mathematically model its ozone release rate, and test its capability in the degradation of pollutants. From the results, it was found that by defining a set of dimensionless parameters, including β-CD to ozone molar ratio and various degrees of ozone saturation, the steady-state conditions in the O3-βCD system can be represented by a newly developed dimensionless plot. In an optimal condition, the dissolved ozone release rate of 6.8 × 10−5 mM/min can be achieved in the O3-βCD system. A mathematical model was successfully developed to estimate the ozone release rate. In the TPH removal experiments, the effects of β-CD to ozone molar ratio and ozone dosage on the removal efficiency were rigorously examined. Overall, an optimal TPH removal of nearly 90% can be achieved in the treatment of 50 mg/L of TPH in water using this inclusion complex reagent.