Oyster shell-modified lignite composite in globular shape as a low-cost adsorbent for the removal of Pb2+ and Cd2+ from AMD: Evaluation of adsorption properties and exploration of potential mechanisms

Abstract

A low-cost composite adsorption material has been synthesized from fishery wastes and natural minerals to address challenges such as ecological balance destruction caused by high concentrations of Pb and Cd in acid mine drainage (AMD), unreasonable use of low-caloric lignite, and environmental pollution caused by idle accumulation of oyster shells. This new adsorbent can effectively treat AMD by improving acidity and adsorbing Pb2+ and Cd2+. In this study, oyster shell-modified lignite composite in globular shape (OSL-G) was synthesized by using pyrolyzed oyster shell and lignite, with the addition of bentonite adhesive. The adsorption properties of OSL-G on AMD were evaluated, and the potential mechanism of OSL-G repairing AMD was explored. The results showed that when the mass ratio of oyster shell to lignite was 1:1, oyster shell-modified lignite composite (OSL) was synthesized at 900 °C for 20 min. When the adhesive content was 15.50 %, the roasting temperature was 640 °C, and the roasting time was 2.35 h, OSL-G was synthesized and the adsorption effect was the best. The OSL-G could effectively treat AMD with pH 4 ∼ 5 and initial Pb2+ and Cd2+ concentrations of 10 mg/L within 600 min at a dosage of 4 g/L. The OSL-G adsorption process followed the quasi-second-order kinetic model and the Freundlich model. The maximum adsorption saturation capacities of Pb2+ and Cd2+ were 107.2821 mg/g and 8.3777 mg/g at 298.15 K, respectively. The adsorption process was a multistep controlled spontaneous endothermic process. The potential mechanism was mainly the adsorption-condensation coexistence results of electrostatic adsorption, neutralization precipitation, ion exchange, and surface complexation. The removal rates of Pb2+ and Cd2+ of the recovered OSL-G (ROSL-G) were still high, reaching 57.26 % and 50.38 % after 5 times of adsorption–desorption, respectively. The applicability of ROSL-G after adsorption–desorption for other heavy metal components in AMD proved its good application potential. This study suggested that OSL-G can be used as a promising environmentally friendly adsorbent for AMD. This study provided a broad picture of the management and reuse possibilities of fishery wastes and natural mineral resources, and addressed established, current, and potential strategic needs, particularly in terms of sustainability challenges and ecological civilization construction.