Abstract

Oxygen diffusion coefficients have been determined for polycrystalline samples of NiCr2O4 and α‐Fe2O3 by exchange measurements with oxygen gas containing the stable isotope18O, using mass spectrometer analysis. Oxygen diffusion in NiCr2O4 can be represented by the equation D = 0.017 exp (‐65,400/RT); oxygen diffusion in α‐Fe2O3 can be represented by the equation D = 1 × 1011 exp (‐146,000/RT). The large difference between D0 and activation energy for these materials suggests that different diffusion mechanisms are involved.

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