Oxygen Atom Insertion into the Osmium–Carbon Bond via an Organometallic Oxido–Osmium(V) Intermediate

Hideki Sugimoto,Shinobu Itoh,Yoshihito Shiota,Kurumi Aoki,Mayuko Miyanishi,Kazunari Yoshizawa

doi:10.1021/acs.organomet.0c00772

Oxygen Atom Insertion into the Osmium–Carbon Bond via an Organometallic Oxido–Osmium(V) Intermediate

Hideki Sugimoto, Shinobu Itoh + Show 4 more

https://doi.org/10.1021/acs.organomet.0c00772

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Journal: Organometallics	Publication Date: Jan 8, 2021
Citations: 7

Affiliation: Osaka University, Kyushu University

#Oxygen Atom Insertion #Osmium Complex + Show 3 more

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Abstract

A cyclometalated osmium(III) complex, [OsIIICl(phpy)(tpy)]+ (OsIII(phpy); phpy = 2-C6H4-2′-C5H4N-κC,N) is synthesized from OsIIICl3(tpy) (tpy = 2,2′;6′,2″-terpyridine) and 2-phenylpyridine (H-phpy)...

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