Oxygen adsorption on Cu( [formula omitted]10): Determination of atom positions with low energy ion scattering

Abstract

The position of adsorbed oxygen on Cu( 1 10) surfaces was determined with Low Energy Ion Scattering (LEIS). The experiments were performed by bombarding the copper surface at small angles of incidence with low energy Ne + ions (3–5 keV). Measurements of the Ne + ions scattered by adsorbed oxygen showed regular peaks in the azimuthal distribution of the scattered ions due to a shadowing effect. From the symmetry of the azimuthal distributions it follows that the centre of an adsorbed oxygen atom on the Cu(1̄10) surface lies about 0.6 Å below the midpoint between two neighbouring Cu atoms in a 〈001〉 row. A comparison of the azimuthal distributions of Ne + ions scattered from clean Cu surfaces and oxygen-covered Cu surfaces showed that hardly any surface reconstruction had occurred in the oxygen-covered surfaces. The applied method seems to be an appropriate one for locating adsorbed atoms because it uses only simple qualitative considerations about azimuthal distributions of scattered ions.