Abstract
Natural-abundance 17O-NMR spectra of 7-oxanorbornane exo-3-oxatricyclo [3.2.1.0 2.4]octane and their unsaturated derivatives ( endo cyclic and exocyclic double bonds) have been measured. Linear correlation laws were observed for δ o δ c of these ethers/corresponding hydrocarbons. The “cyclization shifts” for δ o in ethers were not correlated by the “cyclization shifts” for δ c of the corresponding hydrocarbons.
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