Abstract
A bifunctional tethered iridium catalyst containing a 1,2-diphenylethylenediamine framework was synthesised for the first time. The ethereal tether chain was easily constructed via the intramolecular oxydefluorination of a perfluorophenylsulfonyl substituent by using a modified 1,2,3,4,5-pentamethylcyclopentadienyl ligand with a hydroxyalkyl chain. The conformationally constrained structure could hamper deactivation pathways in the catalytic hydrogen generation from formic acid, leading to advanced durability and complete conversion.
Published Version
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