Abstract
The reaction of acetoxime, ethyl methyl ketoxime or cyclohexanone oxime with zirconium iso-propoxide gave dimeric alkoxo oximate derivatives [Zr(OiPr)(oximate)₃]₂. The oximate ligands are side-on coordinated and the alkoxo groups bridge the two metal centres. NMR spectroscopy revealed dynamic behaviour of the compounds in solution. When exposing a reaction mixture of zirconium butoxide and cyclohexanone oxime to ambient moisture, the oxo-alkoxo derivative Zr₄O(OBu)₈(ON=C₆H₁₀)₆ was obtained.
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