Abstract

Raman and inelastic electron tunneling spectra of the anchored rhenium complexes [Re(CO) 3{O-Mg}{HO-Mg} 2] and [Re(CO) 3{O-Al}{HO-Al} 2] are reported, providing the first vibrational spectroscopic evidence of the metal-oxygen bond in mononuclear oxide-bound organometallic complexes.

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