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Abstract
A consistent methodology for obtaining the enthalpy of formation of Fe2+-containing binary and multicomponent oxides using high-temperature oxide melt solution calorimetry has been developed. The enthalpies of wüstite (FeO) and magnetite (Fe3O4) oxidation to hematite (Fe2O3) were measured using oxidative drop solution calorimetry in which the final product is dissolved ferric oxide. Two methods were applied: drop solution calorimetry at 1073 K in lead borate solvent and at 973 K in sodium molybdate, each under both oxygen flowing over and bubbling through the solvent, giving consistent results in agreement with literature values. The enthalpies of formation of all three iron oxides from the elements were obtained using a thermodynamic cycle involving the directly measured oxidative dissolution enthalpy of iron metal in sodium molybdate at 973 K and gave excellent consistency with literature data.
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