Abstract
Oxidation of cyclohexenyl hydroperoxide by molecular oxygen in the presence of penta(dimethylsulfoxido)vanadyl hexathiocyanatoplatinate proceeds at a high rate at low temperatures with the formation of bifunctional, oxygen-containing products. The main route of the reaction is the molecular oxidation of the hydroperoxide with ring opening in a complex [Catm...HOORn]; oxidation of cyclohexenyl hydroperoxide to a dihydroperoxide takes place simultaneously by a chain mechanism.
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Schedule a callMore From: Bulletin of the Academy of Sciences of the USSR Division of Chemical Science
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