Abstract
AbstractIf an insoluble polymeric complex 1 which possesses both the bis(ethylene‐1,2‐dithiolato)Cu(II) a Cu(II)phthalocyanine type structure is treated with a pyridine solution of the Cu(II)‐pyridine complex in a low concentration, the filtrate obtains a high activity for the oxidative polymerization of 2,6‐dimethylphenol. This might be due to a partial decomposition followed by a partial dissolution of the polymer complex. The catalytic behaviour of the soluble part of the polymeric complex 1 was studied. The activity of this mixed catalyst system consisting of Cu(II)Py and the soluble part of 1 was found to be 6–50times higher than that of Cu(II)Py alone under the applied conditions.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Disclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.