Abstract
AbstractIf an insoluble polymeric complex 1 which possesses both the bis(ethylene‐1,2‐dithiolato)Cu(II) a Cu(II)phthalocyanine type structure is treated with a pyridine solution of the Cu(II)‐pyridine complex in a low concentration, the filtrate obtains a high activity for the oxidative polymerization of 2,6‐dimethylphenol. This might be due to a partial decomposition followed by a partial dissolution of the polymer complex. The catalytic behaviour of the soluble part of the polymeric complex 1 was studied. The activity of this mixed catalyst system consisting of Cu(II)Py and the soluble part of 1 was found to be 6–50times higher than that of Cu(II)Py alone under the applied conditions.
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