Abstract

2-, 3-, 4-Nitropyridine (1a, i, j) and some simple derivatives of 3-nitropyridine (1b-h) undergo dehydro-methylamination in a solution of potassium permanganate in liquid methylamine. In the case of 2- and 6-chloro and 6-methoxy derivatives of 3-nitropyridine (1b-d) dechloro- or demethoxy-methylamination occurs as well.

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