Abstract

Oxidative desulfurization of naphtha with H2O2 in the presence of H2SO4 in the naphtha/acetic acid (AcOH) biphasic system was investigated. All organosulfur compounds examined were smoothly oxidized in AcOH by peracetic acid effectively formed from AcOH and H2O2 in the presence of H2SO4. The order of the oxidation reactivities was sulfides, disulfides > benzothiophenes > thiophenes. The organosulfur compounds in octane were also oxidized with H2O2 in the presence of H2SO4 in the octane/AcOH biphasic system. The oxidation proceeded in the AcOH phase and most of the oxidized sulfur compounds resided in this phase, resulting in the successive removal of the sulfur compounds from the octane phase. This oxidative treatment effectively reduced the sulfur content of naphtha, and adsorption with silica gel further reduced the sulfur content to below 0.5 mass ppm. In addition, hydrodesulfurization is an effective pretreatment for this oxidative desulfurization of naphtha, resulting in further reduction of the sulfur content to below 0.1 mass ppm.

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