Abstract

The development of heterogeneous catalysts to affect the activation of recalcitrant biomolecules has applications for biomass processing, biomass fuel cells, and wastewater remediation. We demonstrate that a cobalt oxygen evolution catalyst (Co-OEC) can catalyze the oxidation of carbon feedstocks completely to CO2. A quantitative analysis of the product distribution from the oxidative degradation of the C2 compound, ethylene glycol, is elaborated and a reaction sequence is proposed. The Co-OEC is also found to be competent for oxidatively degrading C2+ compounds, including glucose and lignin, to carbon dioxide at consequential Faradaic efficiencies.

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