Abstract
Fe(III) treated K-10 montmorillonite and FeCl3 (both hydrated and anhydrous) are compared as catalysts for oxidative coupling of phenol substrates under a range of conditions. While the commonly reported coupling of 2-naphthol proceeds under a range of conditions, other substrates are far less readily coupled. Counterintuitively, biphasic reactions of poorly water soluble substrates in contact with aqueous solutions of FeCl3 are the most universally applicable conditions while many homogeneous reaction mixtures yield little or no coupling product. Fe(III) treated K-10 proved to be a poor catalyst for oxidative coupling of most substrates. Comparison of coupling conditions provides a framework for optimisation of green methodologies using oxidative coupling catalysts.
Sign-in/Register to access full text options 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
