Abstract

A number of supported catalysts, prepared by depositing alkaline earth (viz. Mg, Ca, Sr and Ba) oxides on a commercial support (SA-5205) precoated with various rare earth (viz. La, Ce, Nd, Sm, Gd, Er and Yb) oxides have been evaluated for their surface properties and activity/selectivity in oxidative coupling of methane (OCM) at low contact time (GHSV=1.02×10 5 cm 3 g −1 h −1). The catalysts have been characterized for their basicity and acidity distributions by temperature programmed desorption (TPD) Of CO 2 and ammonia from 50°C to 950°C, respectively, and for their oxygen chemisorption sites by TPD of O 2. The OCM activity of the catalysts has been correlated with their basic sites measured in terms of the CO 2 desorbed between 500°C and 950°C. The catalysts with La 2O 3 and/or Nd 2O 3, showing good OCM activity, have been compared for their performance in the OCM process at different temperatures (750°C–850°C), and CH 4/O 2 ratios (4.0–20.0) in the feed. At 850°C, the catalyst with SrO deposited on the support precoated with mixed La 2O 3–Nd 2O 3 shows best performance in the OCM process.

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