Abstract
Oxidation leads to macrolactone: Oxidative carbon–carbon bond activation is a key step in the formal synthesis of leucascandrolide A, which is formed in one step from 1. Additional features are stereoselective BiBr3-mediated allylation, acetal formation as a fragment-coupling reaction, and a rhenium-mediated allylic alcohol transposition leading to stable macrolactol formation.
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