Abstract

1. In the oxidation of primary, secondary, and tertiary aliphatic alcohols with the system Pb(OAc)4-metal chloride, the principal product is the δ-chloroalkanol. 2. EPR using spin traps has been used to identify the alkoxyl and secondary C-centered radicals generated in the oxidation.of an alcohol with Pb (OAc)4 and with the system Pb(OAc)4-LiCl.

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