Oxidative Carbonylation of Alkynes in an Oscillation Mode: I. Concentration Limits for Oscillations in the Course of Phenylacetylene Carbonylation and Possible Mechanisms of the Process

S. N. Gorodskii,A. V. Kulik,A. N. Zakharov,L. G. Bruk,O. N. Temkin

doi:10.1023/a:1010477720669

Oxidative Carbonylation of Alkynes in an Oscillation Mode: I. Concentration Limits for Oscillations in the Course of Phenylacetylene Carbonylation and Possible Mechanisms of the Process

S. N. Gorodskii, A. V. Kulik + Show 3 more

https://doi.org/10.1023/a:1010477720669

Copy DOI

Journal: Kinetics and Catalysis	Publication Date: Jan 1, 2001
Citations: 24

Affiliation: Moscow State University of Fine Chemical Technologies, Moscow Architectural Institute

#Oxidative Carbonylation Of Alkynes #Mechanism Of Oscillations + Show 8 more

Abstract
Full-Text PDF
Similar Papers

Abstract

An oscillating reaction of alkyne oxidative carbonylation is studied in a PdI2–KI–CH3OH catalytic system. Concentration limits for oscillations are found. A tentative kinetic model for the process is proposed. The mechanism of oscillations is discussed.

Full Text