Abstract
Abstract The oxidative addition reactions of selenocyanogen with [M(P(C6H5)3)4] (M [dbnd] Pd, Pt) in ethyl ether: pentane:ethanol (5:5:2 by volume) at −78°C under nitrogen lead to the formation of the complexes trans-[M(P(C6H5)3)2 (SeCN)2]. Although the selenocyanates are Se-bound in both complexes in the solid state, dissolution of the Pt(II) complex in methylene chloride or DMF leads to partial isomerization to the N-bonded form.
Sign-in/Register to access full text options 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callMore From: Synthesis and Reactivity in Inorganic and Metal-Organic Chemistry
Disclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
