Abstract
The monomeric subvalent indium(I) complex supported by ligation of the tris(3,5-di-t-butylpyrazolyl)hydroborato ligand, [TpBu t 2 ]In, undergoes oxidative-addition reactions with elemental I2 and S8 to give the indium (III) complexes [TpBu t 2 ]InI2 and [TpBu t 2 ]In(η2-S4), respectively. [TpBu t 2 ]InI2 is monoclinic, P21/ n (No. 14), with a = 26.698(10) A, b = 10.801(3) A, c = 29.192(6) A, β = 92.07(3)°, V = 8412(4) A3 and Z = 8. [TpBu t 2 ]In(η2-S4) is monoclinic, C2/c (No. 15) with a = 38.150(8) A, b = 10.585(2) A, c = 23.984(3) A, β = 109.19(2)°, v = 9165(5) A3 and Z = 8.
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