Abstract
A reaction of Cp′Mo(CO)3Cl(Cp′ = MeC5H4) with (PPh3)2Pt(C2Ph2) gave the heterometallic cluster Cp′Mo(μ-CO)2(C2Ph2)Pt2(PPh3)2(CO)Cl (I) as the sole product. According to X-ray diffraction data, complex I contains single Pt-Mo bonds (2.7962(5) and 2.7699(5) A) but no Pt-Pt bond (Pt…Pt 2.9746(3) A). The coordinated diphenylacetylene molecule forms two Pt-C σ-bonds (2.054(6) and 2.083(5) A) and a π-bond to the Mo atom (Mo-C 2.265(6) and 2.272(5) A; C≡C 1.387(8) A).
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