Abstract
Halogens oxidatively add to MoRu(CO) 6(μ-dppm) 2 ( 1) at ambient temperature to yield [(CO) 2Mo(μ-X)(μ-CO)(μ-dppm) 2Ru(CO) 2] +[Mo(CO) 4X 3] −, where X=Cl ( 2) or I ( 3), dppm=Ph 2PCH 2PPh 2, and the μ-CO is semi-bridging. Complexes 2 and 3 have been characterized by elemental analysis, conductivity, and NMR spectroscopy, while the molecular structure of 3 has been determined by X-ray crystallography. Ignoring a weak metal–metal bond interaction, the cation of 3 is most easily described as pseudo-octahedral at Ru(II) and Mo(0) centres; the anion is a monocapped octahedron that has been described previously.
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