Abstract
Abstract Chemical oxidation of the mercapto carbonyl manganese complexes (Me3P)2(CO)3Mn-SX (1), (Me3P)2(CO)5Mn2(SX)2 (2), and (CO)8Mn2(SX)2 (3) (X = H, SnMe3) were investigated. From the SH complexes no identifiable products could be obtained. For X = SnMe3, the iodine oxidation of 2 yielded (Me3P)2(CO)5Mn2S2 (5), that of 3 gave (CO)15Mn4S4 (7), both containing bridging disulfide ligands. The crystal structure of 7 was determined.
Full Text 
Sign-in/Register to access full text options
Sign-in/Register to access full text options 
Paper version not known
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a call
