Abstract
The electrochemistry of the complex [Fe(CO) 2(NO) 2] and the IR and EPR spectra of the one-electron reduced [Fe(CO) 2(NO) 2] − and one-electron oxidised species [Fe(CO) 2(NO) 2] + reveal mainly NO-centred spin density for the unpaired electron. The results are discussed in term of oxidation states. Furthermore, the parent complex was investigated for light-induced linkage isomerisation using IR spectroscopy. Thermally and optically reversible generation of a new species identified by new vibrational bands is interpreted in terms of photoinduced nitrosyl linkage isomers.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
