Abstract
The synthesis and characterization of the Fe(III) and Co(II/III) complexes of tridentate heteroscorpionate ligands, (2-hydroxyphenyl) bis(pyrazolyl)methane, L1, and its derivatives, L2 and L3 are reported. Complexes prepared include [Fe(L) 2][ClO 4] where L=1–3, [Co(L3) 2], [Co(L3) 2][BPh 4], and [Co(L) 2] 2Ag(MeCN)[BF 4] 3 where L=1 and 2. X-ray crystallographic analysis of several of the complexes have been completed. Electrochemical and other methods show that there is an oxidation state and ligand dependant cis/ trans isomerization in these complexes.
Sign-in/Register to access full text options 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
