Abstract
A corrosion-resistant electrocatalyst support was prepared by overcoating high surface-area diamond powder ( diameter, ) with a thin layer of boron-doped ultrananocrystalline diamond (B-UNCD) by microwave plasma-assisted chemical vapor deposition. This core-shell approach produces electrically conducting and high surface-area diamond powder (B-UNCD-D). Accelerated degradation testing was performed by thermogravimetric analysis (TGA) to assess the oxidation resistance (i.e., corrosion resistance) of powder in the absence and presence of nanoscale Pt. The oxidation onset temperature for B-UNCD-D powder decreased with the Pt loading from . However, compared with the bare powder, the rate of carbon consumption was significantly greater for Pt-(XC-72) as compared to the platinized diamond powder. For example, the temperature of the maximum carbon consumption rate, , occurred at for Pt-(XC-72) (20% Pt/C), which was lower than the for bare XC-72. In contrast, for Pt-(B-UNCD-D, 20% Pt/C) was ; a temperature that was only lower than that for bare diamond. Isothermal oxidation at for produced negligible weight loss for Pt-UNCD-D (20% Pt/C) while a 75% weight loss was observed for Pt-(XC-72) (20% Pt/C). The results clearly demonstrate that platinized diamond is more resistant to gas phase oxidation than is platinized Vulcan at elevated temperatures.
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