Abstract

The low temperature emission of 1O2 singlet oxygen from xV2O5 · yMoO3 binary oxides is investigated by means of flash desorption. Conditions for the generation of 1O2 on their surfaces are determined, along with the correlation between the amount of 1O2 and the degree of NaHSO3 conversion in the oxidation reaction. It is shown that on the surface of oxides there are oxygen species that upon decomposition produce 1O2 involved in the oxidation of HSO3−.

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