Oxidation of molten zirconium droplets in water

Abstract

Zirconium, which is used as the cladding material of nuclear fuel rods in LWRs, can react with steam in the case of a core meltdown accident. This results in the release of hydrogen which poses a significant risk of hydrogen explosion. Oxidation of Zr occurs either during the core degradation when the steam flows over the hot fuel rod surfaces or during an FCI when molten corium falls into a water pool (e.g. in the lower head). An experimental study was performed at the MISTEE-OX facility at KTH to observe and quantify the oxidation of molten zirconium droplets in a water pool. During the experimental runs, single droplets of molten zirconium were discharged into a subcooled water pool and the dynamic events were recorded using a high-speed camera. The bubble dynamics indicate a process of cyclic oxidation and hydrogen release from the rear periphery of a droplet while it is quenched in the water. The debris (solidified state of the droplet) after each run was collected for compositional and microstructural analysis via SEM/EDS. The obtained data were employed to estimate the oxidation fractions of the droplets and the results revealed several interesting insights into the oxidation phenomenon of the Zr melt. The water subcooling was observed to have a significant influence on the oxidation: the degree of oxidation decreased with increase in the water subcooling. Furthermore, the degree of oxidation was also influenced by the depth into the debris, forming compounds whose oxygen content decreases from the outer surface towards the core of the debris. Therefore, the qualitative and quantitative results presented in this paper are important in the context of developing a phenomenological understanding of the oxidation behaviour of zirconium melt during the FCI as well as to improve and validate the currently available models implemented in the state-of-art steam explosion codes.