Abstract
The oxidation kinetics of some para-substituted anilines by benzimidazolium fluorochromate (BIFC) have been studied in aqueous acetic acid media in the presence of perchloric acid. The reaction is first order with respect to both aniline and BIFC and is catalysed by a hydrogen ion. The rate data obey Hammett relationship. The products of oxidation are the corresponding azo benzenes. Based on the kinetic results and product analysis, a suitable mechanism has been proposed for the reaction of BIFC with anilines.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
